Nb–Ta fractionation induced by fluid‐rock interaction in subduction‐zones: constraints from UHP eclogite‐ and vein‐hosted rutile from the Dabie orogen,Central‐Eastern China     

J. HUANG  Y. XIAO  Y. GAO  Z. HOU  W. WU 《Journal of Metamorphic Geology》2012,30(8):821-842

Niobium and Ta concentrations in ultrahigh‐pressure (UHP) eclogites and rutile from these eclogites and associated high pressure (HP) veins were used to study the behaviour of Nb–Ta during dehydration and fluid‐rock interaction. Samples were collected through a ～2 km profile at the Bixiling complex in the Dabie orogenic belt, Central‐Eastern China. All but one eclogite away from veins (EAVs) display nearly constant Nb/Ta ratios ranging from 16.1 to 19.2, with an average of 16.9 ± 0.8 (2 SE), similar to that of their gabbroic protolith from the Yangtze Block. Nb/Ta ratios of rutile from the EAVs range from 12.7 to 25.3 among different individual grains, with the average values close to those of the corresponding bulk rocks. These observations show that Nb and Ta were not significantly fractionated by prograde metamorphism up to eclogite facies when no significant fluid‐rock interaction occurs. In contrast, Nb/Ta ratios of rutile from eclogites close to veins (ECVs) are highly variable from 17.8 to 49.8, which are systematically higher (by up to 17) than those of rutile from the veins. These observations demonstrate that Nb and Ta were mobilized and fractionated during localized fluid flow and intensive fluid‐rock interaction. This is strongly supported by Nb/Ta zoning patterns in single rutile grains revealed by in situ LA‐ICP‐MS analysis. Ratios of Nb/Ta in the ECV‐hosted rutile decrease gradually from cores towards rims, whereas those in the EAV‐hosted rutile are nearly invariable. Furthermore, the vein rutile shows Nb/Ta zoning patterns that are complementary to those in rutile from their immediate hosts (ECVs), suggesting an internal origin for the vein‐forming fluids. The Nb/Ta ratios of such fluids evolved from low values at the early stage of subduction to higher values at later supercritical conditions with increased temperature and pressure. Quantitative modelling was conducted to constrain the compositional evolution of metamorphic fluids during dehydration and fluid‐rock interaction focusing on Nb–Ta distribution. The modelling results based on our proposed multistage fluid phase evolution path can essentially reproduce the natural observations reported in the present study.  相似文献   

Element mobility during continental collision: insights from polymineralic metamorphic vein within UHP eclogite in the Dabie orogen     

Y.‐M. SHENG  Y‐F. ZHENG  S‐N. LI  Z. HU 《Journal of Metamorphic Geology》2013,31(2):221-241

Metamorphic dehydration and partial melting are two important processes during continental collision. They have significant bearing on element transport at the slab interface under subduction‐zone P–T conditions. Petrological and geochemical insights into the two processes are provided by a comprehensive study of leucocratic veins in ultrahigh‐pressure (UHP) metamorphic rocks. This is exemplified by this study of a polymineralic vein within phengite‐bearing UHP eclogite in the Dabie orogen. The vein is primarily composed of quartz, kyanite, epidote and phengite, with minor accessory minerals such as garnet, rutile and zircon. Primary multiphase solid inclusions occur in garnet and epidote from the both vein and host eclogite. They are composed of quartz ± K‐feldspar ± plagioclase ± K‐bearing glass and exhibit irregular to negative crystal shapes that are surrounded by weak radial cracks. This suggests their precipitation from solute‐rich metamorphic fluid/melt that involved the reaction of phengite breakdown. Zircon U–Pb dating for the vein gave two groups of concordant ages at 217 ± 2 and 210 ± 2 Ma, indicating two episodes of zircon growth in the Late Triassic. The same minerals from the two rocks give consistent δ¹⁸O and δD values, suggesting that the vein‐forming fluid was directly derived from the host UHP eclogite. The vein is much richer in phengite and epidote than the host eclogite, suggesting that the fluid is associated with remarkable concentration of such water‐soluble elements as LILE and LREE migration. Garnet and rutile in the vein exhibit much higher contents of HREE (2.2–5.7 times) and Nb–Ta (1.8–2.0 times) than those in the eclogite, indicating that these normally water‐insoluble elements became mobile and then were sunken in the vein minerals. Thus, the vein‐forming agent would be primarily composed of the UHP aqueous fluid with minor amounts of the hydrous melt, which may even become a supercritical fluid to have a capacity to transport not only LILE and LREE but also HREE and HFSE at subduction‐zone metamorphic conditions. Taken together, significant amounts of trace elements were transported by the vein‐forming fluid due to the phengite breakdown inside the UHP eclogite during exhumation of the deeply subducted continental crust.  相似文献   

山东招远罗山金矿控矿断裂成因,演化及其意义     

章增凤  张亚雄 《华东地质学院学报》1989,12(3):13-21

  相似文献   

三山岛金矿F3断裂带的水文地质工程地质特征及灾害防治   总被引：2，自引：0，他引：2  

张寿全  黄巍 《工程地质学报》1994,2(1):62-72

本文对三山岛金矿F3断裂带的构造、岩性和水动力学特征进行了研究,对矿坑开挖中的突水和坑道碎屑流的成因做了探讨,并在水文地质结构、水化学、水同位素及水文地热学的综合研究基础上,对未来的二期井下工程开挖中可能出现的工程地质问题进行了预测,提出了防治方案。  相似文献   

河北张－宣金矿区含金石英脉⁴⁰Ar/³⁹Ar年龄   总被引：19，自引：1，他引：19       下载免费PDF全文

胡达骧  罗桂玲 《地质科学》1994,29(2):151-158

为解决张-宣地区含金石英脉形成的时代,对区内5个典型金矿脉测定了⁴⁰Ar/³⁹Ar年龄,分别为:1362.0±24.8Ma,963.7±22.3Ma,579.6±8.5Ma,570.8±24.2Ma,167.9±1.2Ma.谱线特征均为马鞍形,最低视年龄为石英的结晶年龄。依次相当于晋宁运动中期,晋宁运动晚期,蓟县运动晚期和燕山运动中期。  相似文献   

广西水岩坝矿田成矿构造演化及脉型矿床的构造控矿机制研究   总被引：2，自引：1，他引：2  

谢国源  胡火炎 《大地构造与成矿学》1994,18(1):75-83

位于桂东北姑婆山复式岩体西南接触带的水岩坝锡钨矿田，其主要矿床在控矿因素上具有以构造控矿为主导因素的特点，本文通过对矿田内主干断裂的岩组运动学、动力学及变形岩石有限应变分析。对本区自地洼区阶段以来，燕山期花岗岩体的侵入所造成的矿田构造格局进行了系统的研究；然后．根据烂头山黑钨石英脉型矿床的特征，按脆－韧性剪切的原理，从递进变形的角度指出本区脉型矿床的成矿规律．模式和找矿方向，并提出该矿床为构控型多因复成矿床。  相似文献   

德兴斑岩铜矿成矿过程中地下热水运移的动力学模拟   总被引：4，自引：1，他引：4  

郭国章  任启江 《地球化学》1994,23(4):402-410

按照质量，动量和能量守恒定律建立描述成矿流体运移过程的控制微分方程组，运用有限元方法求解，得到有关成矿流体运移的流函数和温度分布值，将上述理论应用于江西德兴斑岩铜矿区，取得了满意的效果。  相似文献   

小秦岭石英脉（构造带）含金性评价的包裹体指标研究     

卿敏  白万成 《黄金地质》1995,1(3):54-60

选择了小秦岭含金石英脉脉石英的显微镜下特征、红外光谱及近脉（矿）围岩全岩爆裂温测等３种包裹体研究方法，对比研究了东闯金、铅矿区和杨砦峪矿区不同含金性石英脉、含矿脉中的富矿、贫矿地段及矿体不同部位的包裹体特征，提出出了石英脉含金性评价及差别矿体剥蚀程度的包裹体指标。  相似文献   

高密度电阻率法在东安金矿床勘探中的应用     

张海心  杨言辰 《吉林地质》2005,24(4):76-79

本文论述了高密度电阻率法在逊克县东安岩金矿床勘探中的应用效果;阐明了该方法在地质勘查中解决高阻脉状金矿体产状及埋深的技术手段.  相似文献   

宾川幔坳区斑岩铜矿综合信息三维找矿模型   总被引：2，自引：2，他引：2  

曹显光 《云南地质》2002,21(4):353-364

云南宾川幔坳区位于青藏高原横断山脉东缘，金沙江有色贵金属矿带南段，是云南仅次于东川-昭通，个旧-丘北的第三大幔坳区，本文首次概括综合信息三维找矿模型显示，该区可能赋存一个超大型斑岩系列铜矿床，区内纳米碳，铜，金相互作用是其主要成矿作用之一。  相似文献